◉ Introduction to POPs Regulations
POPs is the abbreviation of English (Persistent Organic Pollutants), and the Chinese name is "persistent organic pollutants". It refers to environmental persistence, bioaccumulation, long-distance migration, and potential toxicity. , natural or synthetic organic matter that is capable of long-distance transboundary movement through air, water and migratory species and deposited far from other discharge sites, and that can accumulate in terrestrial and aquatic ecosystems with negative effects on the environment and organisms .
In 2004, the EU promulgated the Persistent Organic Pollutants Regulation (POPs Regulation) (EC) No 850/2004, which proposed specific control measures for the use of POPs in the EU. Since then, the European Commission has revised the POPs regulations for many times, bringing a variety of persistent organic pollutants commonly used in the industrial and consumer products into the regulatory control, many of which are widely used in the electrical and electronic industry. On June 25, 2019, the European Union issued a new POPs Regulation (EU) 2019/1021, which came into effect on July 15, 2019, and the original Regulation (EC) No 850/2004 was repealed.
◉ Hazards of POPs
(1) The impact on the birth weight of children may lead to a decrease in the birth weight of human infants, stunting, skeletal developmental disorders and metabolic disorders, which can all have an impact on human life.
(2) Disorders of the nervous system, attention, and inhibition of the immune system.
(3) Harm to the reproductive system. It also has potential threats to the endocrine system of the human body, leading to testicular cancer in men, decreased sperm count, abnormal reproductive function, imbalance of sex ratio in newborns, breast cancer in women, early puberty, etc., which not only harms the individual, but also causes harm to their offspring. cause permanent effects.
(4) Effects on cancer.
◉ Regulation Annex
The EU POPs regulation contains five annexes, namely:
Annex I List of Prohibited Substances
Annex II List of Restricted Substances
Annex III List of Substances Reducing Emissions
List of substances subject to waste management regulations in Annex IV, Article 7
Annex V Waste Management
◉ Scope of Control
Including such as chemical products, electrical and electronic products, toys, automobiles, textiles, furniture and other products.
◉ List of controlled substances under POPs regulations (33 items)
|
Serial number |
English name of substance |
CAS number |
Date of inclusion |
|
1 |
Tetrabromodiphenyl ether |
40088-47-9 |
2010.08.24 |
|
2 |
Pentabromodiphenyl ether |
32534-81-9 |
2010.08.24 |
|
3 |
Hexabromodiphenyl ether |
36483-60-0 |
2010.08.24 |
|
4 |
Heptabromodiphenyl ether |
68928-80-3 |
2010.08.24 |
|
5 |
Decabromodiphenyl ether |
1163-19-5 |
2019.06.20 |
|
6 |
1,1,1-trichloro-2,2-bis (4-chlorophenyl) ethane |
50-29-3 |
2004.04.29 |
|
7 |
Chlordane |
57-74-9 |
2004.04.29 |
|
8 |
Hexachlorocyclohexanes, including lindane |
58-89-9 and other |
2004.04.29 |
|
9 |
Dieldrin |
60-57-1 |
2004.04.29 |
|
10 |
Endrin |
72-20-8 |
2004.04.29 |
|
11 |
Heptachlor |
76-44-8 |
2004.04.29 |
|
12 |
Chlordecone |
143-50-0 |
2004.04.29 |
|
13 |
Aldrin |
309-00-2 |
2004.04.29 |
|
14 |
Mirex |
2385-85-5 |
2004.04.29 |
|
15 |
Toxaphene |
8001-35-2 |
2004.04.29 |
|
16 |
Endosulfan |
115-29-7 and other |
2012.06.19 |
|
17 |
Dicofol |
115-32-2 |
2020.08.18 |
|
18 |
Pentachlorobenzene |
608-93-5 |
2010.08.24 |
|
19 |
Polychlorinated biphenyls |
1336-36-3 and others |
2004.04.29 |
|
20 |
Hexabromobiphenyl |
36355-01-8 |
2004.04.29 |
|
21 |
Hexachlorobutadiene |
87-68-3 |
2012.06.19 |
|
22 |
Polychlorinated Naphthalenes |
70776-03-3 and others |
2012.06.19 |
|
23 |
Hexachlorobenzene |
118-74-1 |
2004.04.29 |
|
24 |
ShortChain Chlorinated Paraffins |
85535-84-8 |
2012.06.19 |
|
25 |
Hexabromocyclododecane and all major diastereoisomersidentified: |
25637-99-4 and others
|
2016.03.01 |
|
26 |
Pentachlorophenol and its salts and esters |
87-86-5 and others |
2019.06.20 |
|
27 |
Perfluorooctane sulfonate (PFOS), its salts and related compounds |
1763-23-1 and other |
2010.08.24 |
|
28 |
Perfluorooctanoic acid (PFOA), its salts and related compounds |
335-67-1 and others |
2020.06.15 |
|
29 |
Perfluorohexane Sulfonate (PFHxS), its salts and related compounds |
355-46-4 |
2023.08.08 |
|
30 |
Methoxychlor |
72-43-5 and others |
2024.09.27 |
|
31 |
2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentylphenol |
25973-55-1
|
2025.07.15 |
|
32 |
Dechlorane Plus |
13560-89-9 135821-03-3 135821-74-8 |
2025.09.25 |
|
33 |
Chlorpyrifos |
2921-88-2 |
2026.09.30 |
◉ Common applications of partially controlled substances
|
Substance Name |
Limit Requirements |
Common Applications |
|
(Aldrin), (Chlordane), (DDT), (Dieldrin), (Endrin), (Heptachlor) , (Endosulfan), (Toxaphene), (Hexachlorocyclohexanes,including lindane), (Chlordecone), (Mirex), (Dicofol) |
prohibit |
Insecticide |
|
(Pentachlorobenzene) |
prohibit |
·Dye carrier ·Fungicide ·Flame retardant
|
|
(Hexa-BB) |
prohibit |
flame retardant |
|
(Polychlorinated naphthalenes,PCN) |
prohibit |
· Wood preservatives ·Additives for paint and machine lubricants ·Used as cable and capacitor insulator |
|
(Hexachlorobutadiene,HCBD) |
prohibit |
fungicide |
|
(Polychlorinated Biphenyls,PCBs) |
prohibit |
·Heat transfer fluid paint for transformers and capacitors ·Carbonless copy paper Additives in sealants and plastics |
|
(Hexachlorobenzene,HCB) |
prohibit |
fungicide |
|
Pentachlorophenol (PCP) and its salts and esters |
≤5 mg/kg in substances, mixtures and articles |
flame retardant剂 |
|
(Deca-BDE) |
·≤10 ppm in substance ·The sum of tetra-, penta-, hexa-, hepta- and decabromodiphenyl ethers in mixtures and articles must not exceed 500 mg/kg Except for products within the scope of RoHS control |
flame retardant剂 |
|
(Tetra-BDE) |
flame retardant剂 |
|
|
(Penta-BDE) |
flame retardant剂 |
|
|
(Hexa-BDE) |
Preservatives and fungicides |
|
|
(Hepta-BDE) |
flame retardant |
|
|
(HBCDD) |
The concentration of substances, mixtures and articles must not exceed 100 mg/kg |
flame retardant |
|
(Alkanes C10-C13, chloro (short-chain chlorinated paraffins), SCCPs) |
·Mixture: 1% ·Item: 1500ppm |
·Metal working fluid ·Sealants ·Plastic and textile flame retardant ·Leather craft · In paints and coatings |
|
PFOS and its derivatives Metal salts, halides, amides or other derivatives containing polymers
|
·Mixtures ≤ 10 ppm ·Item ≤ 1000 ppm; ·Textile or coated material≤1ug/m2 |
Antifouling, oil and water repellent additives |
|
PFOA, its salts and PFOA-related substances |
In the substance, mixture or article: ·PFOA and its salts ≤0.025mg/kg; ·PFOA related substances≤1mg/kg |
Antifouling, oil and water repellent additives |
◉ Which POPs substances should electronic products focus on?
For electronic products such as mobile phones, computers, TVs and other electronic products that do not involve the use of natural materials, it is necessary to focus on the risk of containing HBCDD and SCCP in flame-retardant components such as casings, wires and PCBs; non-metals, especially fluoropolymer materials contain PFOS, Risk of PFOA, its salts and PFOA-related substances.
◉ Compliance Services
As a professional third-party testing technology service provider, Jiayu Testing boasts qualifications such as CMA, CNAS, CPSC, and CCC. Additionally, we have obtained laboratory accreditation from multiple authoritative certification bodies both domestically and internationally. Our laboratory is constructed and managed in strict accordance with standards, equipped with advanced instruments and equipment, and staffed by a skilled and professional technical team. We possess extensive industry service experience and robust testing technical capabilities, are proficient in various regulatory standards, and assist enterprises in actively responding to regulatory requirements. We help enterprises achieve hazardous substance risk management and control, effectively enhancing product compliance. Welcome to contact us. Jiayu Testing's consultation hotline is: 400-9269-886!
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